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研究PM2.5中NO3-、NO2-、NH4+及其气态前体物HNO3HNO2、NH3的浓度特征和气-粒平衡关系,对深入认识PM2.5的来源及控制因素具有重要意义.因此,本文利用2012年6—7月在青岛采集的denuder和PM2.5大气样品,分析了其中气态和颗粒态氮组分的浓度.结果发现,青岛大气中HNO3HNO2和NH3浓度分别为(0.80±0.79) μg·m-3、(0.49±0.59) μg...
Observations of NO, NO2, total peroxy nitrates (ΣPNs), total alkyl nitrates (ΣANs), HNO3, CO, O3, and meteorological parameters were obtained from October 2000 through February 2002 at 1315 m a.s.l., ...
The uptake of HNO3 to deliquescent airborne sea-salt particles (RH = 55%, P = 760 torr, T = 300 K) at concentrations from 2 to 575 ppbv is measured in an aerosol flow tube using 13N as a tracer. Small...
The EU-project MINATROC (MINeral dust And TROpospheric Chemistry) aims at enabling an estimation of the influence of mineral dust, a major, but to date largely ignored component of tropospheric aeroso...
Micrometeorological measurements of size-segregated particle number fluxes above Dutch heathlands and forests have repeatedly shown simultaneous apparent emission of particles with a diameter (Dp)<0.1...
A field measurement campaign was carried out over a Dutch heathland to investigate the effect of gas-to-particle conversion and ammonium aerosol evaporation on surface/atmosphere fluxes of ammonia and...
The effect of nitric acid on the equilibrium size distributions of upper tropospheric aerosols is calculated as a function of relative humidity. It is shown that HNO3 concentrations above a few tenths...
For the treatment of soot by pure HNO3 only reversible uptake with a surface coverage of ~1-2x1014 HNO3 cm-2 was observed for HNO3 mixing ratios in the range 250-800ppbv. Only for higher HNO3 mixing r...
Using new and accurate experimental results concerning the spectroscopic properties of the HNO3 molecule as well as improved theoretical methods it has been possible to generate an improved set of lin...
In this paper we study the impact of the modelling of N2O on the simulation of NO2 and HNO3 by comparing in situ vertical profiles measured at mid-latitudes with the results of the Reprobus 3-D CTM (T...
Low-resolution atmospheric thermal emission spectra collected by balloon-borne radiometers over the time span of 1990–2002 are used to retrieve vertical profiles of HNO3, CFC-11 and CFC-12 volume mix...
Nitric acid (HNO3) is one of the key products that are operationally retrieved by the European Space Agency (ESA) from the emission spectra measured by the Michelson Interferometer for Passive Atmosp...
Within the framework of the Network for Detection of Atmospheric Composition Change (NDACC), regular ground-based Fourier transform infrared (FTIR) measurements of many species are performed at severa...
We have studied the impact of the recently observed reaction NO+HO2→HNO3 on atmospheric chemistry. A pressure and temperature-dependent parameterisation of this minor channel of the NO+HO2→NO2+OH reac...
Measurements of exchange of reactive nitrogen oxides between the atmosphere and a ponderosa pine forest in the Sierra Nevada Mountains are reported. During winter, we observe upward fluxes of NO2, and...

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