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Extensive structural studies of enzymes have revealed that biological catalysis occurs within sequestered active site crevices, where reacting substrates are surrounded by an anisotropic and chemicall...
We recently introduced methods to tether phospholipid vesicles or proteoliposomes onto a fluid-supported lipid bilayer using DNA hybridization (Yoshina-Ishii, C.; Miller, G. P.; Kraft, M. L.; Kool, E....
A thermodynamic model describing multicomponent fluid membranes under the influence of lateral forces due to a buried charge is developed to estimate the magnitude and dynamics of field-induced latera...
A thermodynamic model of multicomponent fluid membranes under the influence of lateral forces is described. Membrane components are characterized by their effective molecular areas, molecular charges,...
Electric fields can induce lateral reorganization of lipids in fluid bilayer membranes. The resulting concentration profiles readily are observed in planar-supported bilayers by epifluorescence micros...
Application of electric fields tangent to the plane of a confined patch of fluid bilayer membrane can create lateral concentration gradients of the lipids. A thermodynamic model of this steady-state b...
A simple method of generating electric field-induced concentration gradients in planar supported bilayers has been developed. Gradients of charged, fluorescently labeled probes were visualized by epif...
The rates of electron-transfer reactions can be systematically varied by application of external electric fields. The electric field effect on the charge recombination rate constant of the state P[sup...
The dependence of the rate constant for electron transfer on energy can be systematically studied by measuring kinetics in an applied electric field. General relationships are developed between observ...
Electron-transfer reactions are expected to be particularly sensitive to externally applied electric fields because of the presence of charge-separated, dipolar states, and the effects of the field on...
The effect of an applied electric field on the kinetics of the initial picosecond electron-transfer reaction in Rb. sphaeroides reaction centers has been measured in isotropic samples at 77 K. The net...
A general method is demonstrated for experimentally obtaining the rate constant of electron transfer as a function of the free energy of the reaction in nonoriented systems. An external electric field...
The fluorescence intensity from randomly oriented, immobilized Rb. sphaeroides reaction centers at 77 K increases in the presence of an externally applied electric field. We have proposed that this in...
The fluorescence intensity from randomly oriented Rhodobacter ( Rb.) sphaeroides photosynthetic reaction centers at 77 K increases in an applied electric field. This is ascribed to a net reduction in ...
Power spectrum of the diurnal variations of the quasi-electrostatic field Ez in the near-Earth atmosphere have been presented for the first time. The Ez power spectrum variations in the period of fine...

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